Division I – Eastern Arizona College
Eastern Arizona College secured an at-large berth to the 2025 NJCAA DI Volleyball National Championships and will enter the tournament as the No. 13 seed. The Gila Monsters open play against No. 4 Northeastern Junior College on Wednesday, Nov. 19 at 6 p.m. MST. This year's DI championship will be held in Clarksville, Tennessee.

Division II – Mesa Community College
Mesa Community College earned the No. 9 seed in the 2025 NJCAA DII Volleyball National Championships. The Thunderbirds will face No. 8 Gulf Coast State College in their opening match on Wednesday, Nov. 19 at 12 p.m. MST. The DII championship will take place in Cedar Rapids, Iowa.

Both ACCAC programs will begin bracket play on Nov. 19 as they look to advance through the national tournament fields.